JWST reveals widespread CO ice and gas absorption in the Galactic Center cloud G0.253+0.016

We report JWST NIRCam observations of G0.253+0.016, the molecular cloud in the Central Molecular Zone known as The Brick, with the F182M, F187N, F212N, F410M, F405N, and F466N filters. We catalog 56,146 stars detected in all 6 filters using the crowdsource package. Stars within and behind The Brick exhibit prodigious absorption in the F466N filter that is produced by a combination of CO ice and gas. In support of this conclusion, and as a general resource, we present models of CO gas and ice and CO$_2$ ice in the F466N, F470N, and F410M filters. Both CO gas and ice may contribute to the observed stellar colors. We show, however, that CO gas does not absorb the Pf$\beta$ and Hu$\epsilon$ lines in F466N, but that these lines show excess absorption, indicating that CO ice is also present and contributes to observed F466N absorption. The most strongly absorbed stars in F466N are extincted by $\sim$ 2 magnitudes, corresponding to $>$ 80\% flux loss. This high observed absorption requires very high column densities of CO, requiring total CO column that is in tension with standard CO abundance and/or gas-to-dust ratios. There is therefore likely to be a greater CO/H$_2$ ratio (X$_{CO} > 10^{-4}$) and more dust per H$_2$ molecule ($>0.01$) in the Galactic Center than the Galactic disk. Ice and/or gas absorption is observed even in the cloud outskirts, implying that additional caution is needed when interpreting stellar photometry in filters that overlap with ice bands throughout our Galactic Center. The widespread CO absorption in our Galactic Center hints that significant ice absorption is likely present in other galactic centers.