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arxiv: mtrl-th/9604002 · v1 · pith:7EKJGCTCnew · submitted 1996-04-10 · mtrl-th · atom-ph· chem-ph· cond-mat.mtrl-sci

On The Low-Frequency Vibrational Modes of C₆₀

classification mtrl-th atom-phchem-phcond-mat.mtrl-sci
keywords modesshellelasticfindfrequencysphericalapproxomega
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The vibrational spectrum of C$_{60}$ is compared to the spectrum of a classical isotropic elastic spherical shell. We show correlations between the low frequency modes of C$_{60}$ and those of the spherical shell. We find the spherical model gives the approximate frequency ordering for the low frequency modes. We estimate a Poisson ratio of $\sigma\approx 0.30$ and a transverse speed of sound of $v_s\approx 1800$ m/s for the equivalent elastic shell. We also find that $\omega({\rm M_1})/\omega({\rm M_0})=\sqrt{3\over 2}$ for the shell modes ${\rm M_0}$ and ${\rm M_1}$, independent of elastic constants. We find that this ratio compares favorably with an experimental value of 1.17.

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