The Reionization of Carbon

Observations suggest that CII was more abundant than CIV in the intergalactic medium towards the end of the hydrogen reionization epoch. This transition provides a unique opportunity to study the enrichment history of intergalactic gas and the growth of the ionizing background (UVB) at early times. We study how carbon absorption evolves from z=10-5 using a cosmological hydrodynamic simulation that includes a self-consistent multifrequency UVB as well as a well-constrained model for galactic outflows to disperse metals. Our predicted UVB is within 2-4 times that of Haardt & Madau (2012), which is fair agreement given the uncertainties. Nonetheless, we use a calibration in post-processing to account for Lyman-alpha forest measurements while preserving the predicted spectral slope and inhomogeneity. The UVB fluctuates spatially in such a way that it always exceeds the volume average in regions where metals are found. This implies both that a spatially-uniform UVB is a poor approximation and that metal absorption is not sensitive to the epoch when HII regions overlap globally even at column densites of 10^{12} cm^{-2}. We find, consistent with observations, that the CII mass fraction drops to low redshift while CIV rises owing the combined effects of a growing UVB and continued addition of carbon in low-density regions. This is mimicked in absorption statistics, which broadly agree with observations at z=6-3 while predicting that the absorber column density distributions rise steeply to the lowest observable columns. Our model reproduces the large observed scatter in the number of low-ionization absorbers per sightline, implying that the scatter does not indicate a partially-neutral Universe at z=6.