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arxiv: 1806.07816 · v2 · pith:AQ4243W3new · submitted 2018-06-16 · ❄️ cond-mat.stat-mech

Non-equilibrium thermodynamics as gauge fixing

classification ❄️ cond-mat.stat-mech
keywords gaugeequationsnon-equilibriumthermodynamicsconstitutiveforcethermodynamicextend
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By considering a thermodynamic force as gauge field, we extend constitutive equations of Onsager's non-equilibrium thermodynamics to non-linear equations. In Onsager's non-equilibrium thermodynamics, the thermodynamic force corresponds to a pure gauge, for which the constitutive equations are obtained by gauge fixing. If we extend the thermodynamic force from pure gauge to physical one, we obtain the non-linear constitutive equations of non-equilibrium thermodynamics.

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