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arxiv: 1609.02308 · v1 · pith:AR44OZ4Bnew · submitted 2016-09-08 · ⚛️ physics.flu-dyn · physics.chem-ph

Braun-Le Chatelier principle in dissipative thermodynamics

classification ⚛️ physics.flu-dyn physics.chem-ph
keywords principlethermodynamicsbraun-lechatelierconvexitydissipativeequilibriumfollows
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Braun-Le Chatelier principle is a fundamental result of equilibrium thermodynamics, showing how stable equilibrium states shift when external conditions are varied. The principle follows from convexity of thermodynamic potential. Analogously, from convexity of dissipation potential it follows how steady non-equilibrium states shift when thermodynamic forces are varied, which is the extension of the principle to dissipative thermodynamics.

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