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Raman scattering investigation of superconducting Ba$_{2}$Ti$_{2}$Fe$_{2}$As$_{4}$O

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arxiv 1403.7590 v1 pith:B6TF6FEM submitted 2014-03-29 cond-mat.supr-con cond-mat.str-el

classification cond-mat.supr-concond-mat.str-el
keywords ramanatomsmodeplanesscatteringsuggestaccordanceactive
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abstract

We have performed polarized Raman scattering measurements on the newly discovered superconductor Ba$_{2}$Ti$_{2}$Fe$_{2}$As$_{4}$O$_{2}$ ($T_c = 21$ K). We observe seven out of eight Raman active modes, with frequencies in good accordance with first-principle calculations. The phonon spectra suggest neither strong electron-phonon nor spin-phonon coupling and vary only slightly with temperature, except for one E$_g$ mode associated with large displacements of As atoms near the Ti$_2$O planes. We also identify a small anomaly around 125 K in the linewidth of a A$_{1g}$ mode involving the same As atoms. Our results suggest that the transition at 125 K is most likely driven by electronic interactions taking place in the Ti$_2$O planes.

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