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arxiv: 1306.0838 · v1 · pith:BPECKREEnew · submitted 2013-06-04 · ⚛️ physics.atm-clus · physics.atom-ph

Dipole transitions in the bound rotational-vibrational spectrum of the heteronuclear molecular ion HD^+

classification ⚛️ physics.atm-clus physics.atom-ph
keywords vibrationalbounddigitsdipoleenergiesfunctionsgivenheteronuclear
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The non-relativistic three-body Schr\"odinger equation of the heteronuclear molecular ion HD$^+$ is solved in perimetric coordinates using the Lagrange-mesh method. Energies and wave functions of the four lowest vibrational bound or quasibound states $v=0-3$ are calculated for total orbital momenta from 0 to 47. Energies are given with an accuracy from about 12 digits for the lowest vibrational level to at least 9 digits for the third vibrational excited level. With a simple calculation using the corresponding wave functions, accurate dipole transition probabilities per time unit between those levels are given over the whole $v=0-3$ rotational bands. Results are presented with six significant figures.

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