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Gibbs Paradox and the Concepts of Information, Symmetry, Similarity and Their Relationship

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arxiv 0803.2571 v1 pith:CQBAYLFU submitted 2008-03-18 physics.chem-ph

classification physics.chem-ph
keywords informationentropytheoryamountdataidealsolidchange
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Information (I) is defined as the amount of the data after data compression. The first law of information theory: the total amount of data L (the sum of entropy S and information I) of an isolated system remains unchanged. The second law of information theory: Information I of an isolated system decreases to a minimum at equilibrium. The third law of information theory: For a solid structure of perfect symmetry (e.g., a perfect crystal), the information I is zero and the (information theory) entropy (called by me as static entropy for solid state) S is at the maximum. Gibbs Paradox has been resolved. Spontaneously mixed substances at gaseous state can be spontaneously separated at condensed phases (solid or liquid states), driving only by information loss or by the increase in (information theory) entropy. None of the typical pure mixing or separation processes are driving by free energy minimization and the free energy (or total amount of chemical potential) has no change during the processes of ideal mixture formation or ideal mixture separation. The thermodynamic entropy change for the formation of ideal mixtures of gases, liquids or solids is always zero.

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  1. Solving the Gibbs Paradox by Local Free Space and Collision Potential

    cond-mat.stat-mech 2026-08 reject novelty 4.0 of 10

    The paper derives a new formula for gas-mixture entropy increase that depends on molecular properties, but the derivation contains algebraic errors and predicts negative entropy for common gas pairs.

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