The Crooks relation in optical spectra - universality in work distributions for weak local quenches

We show that work distributions and non-equilibrium work fluctuation theorems can be measured in optical spectra for a wide class of quantum systems. We consider systems where the absorption or emission of a photon corresponds to the sudden switch on or off of a local perturbation. For the particular case of a weak local perturbation, the Crooks relation establishes a universal relation in absorption as well as in emission spectra. Due to a direct relation between the spectra and work distribution functions this is equivalent to universal relations in work distributions for weak local quenches. As two concrete examples we treat the X-ray edge problem and the Kondo exciton.