Epitaxial growth and scanning tunneling microscopy of LiV₂O₄ thin films on SrTiO₃(111)

LiV$_2$O$_4$ is a mixed-valent spinel oxide and one of a few transition-metal compounds to host a heavy fermion phase at low temperatures. While numerous experimental studies have attempted to elucidate how its 3$d$ electrons undergo giant mass renormalization, spectroscopic probes that may provide crucial hints, such as scanning tunneling microscopy (STM), remain to be applied. A prerequisite is atomically flat and pristine surfaces, which, in the case of LiV$_2$O$_4$, are difficult to obtain by cleavage of small, three-dimensional crystals. We report the epitaxial growth of LiV$_2$O$_4$ thin films with bulklike properties on SrTiO$_3$(111) via pulsed laser deposition and stable STM imaging of the LiV$_2$O$_4$(111) surface. The as-grown films were transferred $ex$ $situ$ to a room-temperature STM, where subsequent annealing with optional sputtering in ultrahigh vacuum enabled compact islands with smooth surfaces and a hexagonal 1$\times$1 atomic lattice to be resolved. Our STM measurements provide insights into growth mechanisms of LiV$_2$O$_4$ on SrTiO$_3$(111), as well as demonstrate the feasibility of performing surface-sensitive measurements of this heavy fermion compound.