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Electrodeposition as a new route to synthesize superconducting FeSe

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arxiv 1205.6378 v1 pith:DR3UXVXK submitted 2012-05-29 cond-mat.supr-con

classification cond-mat.supr-con
keywords fesecompositiondepositionelectrochemicalratiosuperconductingsynthesizedvoltage
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We have successfully synthesized FeSe films by the electrochemical deposition in the electrolyte containing FeCl_{2}\cdot4H_{2}O, SeO_{2} and Na_{2}SO_{4}. The composition ratio of Fe and Se was controlled by the synthesis voltage and pH value. The FeSe film with the composition ratio of Fe : Se = 1 : 1 is fabricated at a voltage of -0.9 V and pH 2.1 in our electrochemical deposition. This sample has a highly crystalline tetragonal FeSe structure and exhibits a superconducting transition at 8.1 K, comparable to FeSe synthesized by other methods.

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