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arxiv: 1208.2227 · v2 · pith:EP6K3OYJnew · submitted 2012-08-10 · ❄️ cond-mat.soft · cond-mat.dis-nn

Nonlinear dielectric response at the excess wing of glass-forming liquids

classification ❄️ cond-mat.soft cond-mat.dis-nn
keywords nonlineardielectricexcesswingbehaviorfrequenciesglass-forminghigh
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We present nonlinear dielectric measurements of glass-forming glycerol and propylene carbonate applying electrical fields up to 671 kV/cm. The measurements extend to sufficiently high frequencies to allow for the investigation of the nonlinear behavior in the regime of the so-far mysterious excess wing, showing up in the loss spectra of many glass formers as a second power law at high frequencies. Surprisingly, we find a complete lack of nonlinear behavior in the excess wing, in marked contrast to the alpha-relaxation where, in agreement with previous reports, a strong increase of dielectric constant and loss is found.

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