pith. sign in

arxiv: 1110.6733 · v1 · pith:EPOMI2YRnew · submitted 2011-10-31 · ❄️ cond-mat.soft

Note: Scale-free center-of-mass displacement correlations in polymer films without topological constraints and momentum conservation

classification ❄️ cond-mat.soft
keywords center-of-masschainwithoutconservationconstraintsdirectlydisplacementfilms
0
0 comments X
read the original abstract

We present here computational work on the center-of-mass displacements in thin polymer films of finite width without topological constraints and without momentum conservation obtained using a well-known lattice Monte Carlo algorithm with chain lengths ranging up to N=8192. Computing directly the center-of-mass displacement correlation function C_N(t) allows to make manifest the existence of scale-free colored forces acting on a reference chain. As suggested by the scaling arguments put forward in a recent work on three-dimensional melts, we obtain a negative algebraic decay C_N(t) \sim -1/(Nt) for times t << T_N with T_N being the chain relaxation time. This implies a logarithmic correction to the related center-of-mass mean square-displacement h_N(t) as has been checked directly.

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.