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Interplay of Magnetic Exchange Interactions and Ni-S-Ni Bond Angles in Polynuclear Nickel(II) Complexes

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arxiv 0912.4447 v2 pith:HAERXHTR submitted 2009-12-22 cond-mat.str-el

Interplay of Magnetic Exchange Interactions and Ni-S-Ni Bond Angles in Polynuclear Nickel(II) Complexes

Yulia Krupskaya , Alexey Alfonsov , Anupama Parameswaran , Vladislav Kataev , R\"udiger Klingeler , Gunther Steinfeld , Norman Beyer , Mathias Gressenbuch
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Berthold Kersting Bernd B\"uchner
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classification cond-mat.str-el
keywords magneticcomplexesinteractionsexchangeabilityanglesbeenbond
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The ability of bridging thiophenolate groups to transmit magnetic exchange interactions between paramagnetic Ni(II) ions has been examined. For this purpose, dinuclear and trinuclear Ni(II)-complexes were prepared and fully characterized by IR- and UV-vis spectroscopy, X-ray crystallography, static magnetization measurements and high-field electron spin resonance (HF-ESR). We compare structural and magnetic properties of the two Ni(II)-complexes and discuss the relationships between magnetic interactions and chemical bonding.

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