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arxiv: 1703.05582 · v1 · pith:KWQ5CHWFnew · submitted 2017-03-16 · ❄️ cond-mat.mtrl-sci

Tracking Thermal-Induced Amorphization of a Zeolitic Imidazolate Framework via Synchrotron In Situ Far-Infrared Spectroscopy

classification ❄️ cond-mat.mtrl-sci
keywords amorphizationfar-infraredframeworkimidazolatesituspectroscopyzeoliticanalyze
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We present the first use of in situ far-infrared spectroscopy to analyze the thermal amorphization of a zeolitic imidazolate framework material. We explain the nature of vibrational motion changes during the amorphization process and reveal new insights into the effect that temperature has on the Zn-N tetrahedra.

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