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We present a method to find an optimal policy with respect to a reward function for a discounted Markov decision process under general linear temporal logic (LTL) specifications. Previous work has either focused on maximizing a cumulative reward objective under finite-duration tasks, specified by syntactically co-safe LTL, or maximizing an average reward for persistent (e.g., surveillance) tasks. This paper extends and generalizes these results by introducing a pair of occupancy measures to express the LTL satisfaction objective and the expected discounted reward objective, respectively. These occupancy measures are then connected to a single policy via a novel reduction resulting in a mixed integer linear program whose solution provides an optimal policy. Our formulation can also be extended to include additional constraints with respect to secondary reward functions. We illustrate the effectiveness of our approach in the context of robotic motion planning for complex missions under uncertainty and performance objectives.