Discovery of Charge Order in the Transition Metal Dichalcogenide Fe_(x)NbS₂

The Fe intercalated transition metal dichalcogenide (TMD), Fe$_{1/3}$NbS$_2$, exhibits remarkable resistance switching properties and highly tunable spin ordering phases due to magnetic defects. We conduct synchrotron X-ray scattering measurements on both under-intercalated ($x$ = 0.32) and over-intercalated ($x$ = 0.35) samples. We discover a new charge order phase in the over-intercalated sample, where the excess Fe atoms lead to a zigzag antiferromagnetic order. The agreement between the charge and magnetic ordering temperatures, as well as their intensity relationship, suggests a strong magnetoelastic coupling as the mechanism for the charge ordering. Our results reveal the first example of a charge order phase among the intercalated TMD family and demonstrate the ability to stabilize charge modulation by introducing electronic correlations, where the charge order is absent in bulk 2H-NbS$_2$ compared to other pristine TMDs.