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High-resolution infrared action spectroscopy of the fundamental vibrational band of CN+

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arxiv 2103.00962 v1 pith:MROIWE2B submitted 2021-03-01 physics.chem-ph astro-ph.GA

classification physics.chem-phastro-ph.GA
keywords actionbandbeenfundamentalinfraredspectroscopytrapvibrational
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abstract

Rotational-vibrational transitions of the fundamental vibrational modes of the $^{12}$C$^{14}$N$^+$ and $^{12}$C$^{15}$N$^+$ cations have been observed for the first time using a cryogenic ion trap apparatus with an action spectroscopy scheme. The lines P(3) to R(3) of $^{12}$C$^{14}$N$^+$ and R(1) to R(3) of $^{12}$C$^{15}$N$^+$ have been measured, limited by the trap temperature of approximately 4 K and the restricted tuning range of the infrared laser. Spectroscopic parameters are presented for both isotopologues, with band origins at 2000.7587(1) and 1970.321(1) cm$^{-1}$, respectively, as well as an isotope independent fit combining the new and the literature data.

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