Experimental electronic heat capacities of α- and δ-Plutonium; heavy-fermion physics in an element

We have measured the heat capacities of $\delta-$Pu$_{0.95}$Al$_{0.05}$ and $\alpha-$Pu over the temperature range 2-303 K. The availability of data below 10 K plus an estimate of the phonon contribution to the heat capacity based on recent neutron-scattering experiments on the same sample enable us to make a reliable deduction of the electronic contribution to the heat capacity of $\delta-$Pu$_{0.95}$Al$_{0.05}$; we find $\gamma = 64 \pm 3$ mJK$^{-2}$mol$^{-1}$ as $T \to 0$. This is a factor $\sim 4$ larger than that of any element, and large enough for $\delta-$Pu$_{0.95}$Al$_{0.05}$ to be classed as a heavy-fermion system. By contrast, $\gamma = 17 \pm 1$ mJK$^{-2}$mol$^{-1}$ in $\alpha-$Pu. Two distinct anomalies are seen in the electronic contribution to the heat capacity of $\delta-$Pu$_{0.95}$Al$_{0.05}$, one or both of which may be associated with the formation of the $\alpha'-$ martensitic phase. We suggest that the large $\gamma$-value of $\delta-$Pu$_{0.95}$Al$_{0.05}$ may be caused by proximity to a quantum-critical point.