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arxiv 2306.04194 v1 pith:OGSUU7WG submitted 2023-06-07 physics.optics physics.app-ph

Surface Saturation Current Densities of Perovskite Thin Films from Suns-Photoluminescence Quantum Yield Measurements

classification physics.optics physics.app-ph
keywords thinfilmsperovskitesurfacebimolecularcurrentdensitiesmeasurements
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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We present a simple, yet powerful analysis of Suns-photoluminescence quantum yield measurements that can be used to determine the surface saturation current densities of thin film semiconductors. We apply the method to state-of-the-art polycrystalline perovskite thin films of varying absorber thickness. We show that the non-radiative bimolecular recombination in these samples originates from the surfaces. To the best of our knowledge, this is the first study to demonstrate and quantify non-linear (bimolecular) surface recombination in perovskite thin films.

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