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arxiv: 1206.4932 · v1 · pith:R75MNVVSnew · submitted 2012-06-21 · 🧮 math-ph · math.MP

Existence of Minimizers in Restricted Hartree-Fock Theory

classification 🧮 math-ph math.MP
keywords existencehartree-fockatomsgroundrestrictedtheorychargeclosed
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In this note we establish the existence of ground states for atoms within several restricted Hartree-Fock theories. It is shown, for example, that there exists a ground state for closed shell atoms with $N$ electrons and nuclear charge $Z \geq N-1$. This has to be compared with the general Hartree-Fock theory where the existence of a minimizer is known for $Z>N-1$ only.

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