The dynamic dipole polarizabilities of the Li atom and the Be+ ion
classification
⚛️ physics.atom-ph
physics.chem-ph
keywords
polarizabilitiesatomdipoledynamicanalyticbasiscalculatedcorrections
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The dynamic dipole polarizabilities for the Li atom and the Be+ ion in the 2s and 2p states are calculated using the variational method with a Hylleraas basis. The present polarizabilities represent the definitive values in the non-relativistic limit. Corrections due to relativistic effects are also estimated. Analytic representations of the polarizabilities for frequency ranges encompassing the n=3 excitations are presented. The recommended polarizabilities for ^7Li and ^9Be+ were 164.11 \pm 0.03 a.u. and 24.489 \pm 0.004 a.u..
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