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Spin excitations in the two-dimensional strongly coupled dimer system malachite

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arxiv 1412.5908 v1 pith:RL76HMLF submitted 2014-12-18 cond-mat.str-el

Spin excitations in the two-dimensional strongly coupled dimer system malachite

classification cond-mat.str-el
keywords malachiteantiferromagnetscoupledcouplingdimerexcitationslatticequantum
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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The mineral malachite, Cu2(OD)2CO3, has a quantum spin-liquid ground state and no long-range magnetic order down to at least T=0.4 K. Inelastic neutron scattering measurements show that the excitation spectrum consists of dispersive gapped singlet-triplet excitations, characteristic of spin-1/2 dimer-forming Heisenberg antiferromagnets. We identify a new two-dimensional dimerized coupling scheme with strong interdimer coupling J'/J1~0.3 that places malachite between strongly coupled alternating chains, square lattice antiferromagnets, and infinite-legged ladders. The geometry of the interaction scheme resembles the staggered dimer lattice, which may allow unconventional quantum criticality.

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