The conducting spin-crossover compound combining Fe(II) cation complex with TCNQ in a fractional reduction state

Aleksander V. Korolyov; Alexander I. Kotov; Denis V. Starichenko; Eduard B. Yagubskii; Konstantin A. Lyssenko; Lev I. Buravov; Ludmila G. Lavrenova; Olga G. Shakirova; Vladimir N Zverev; Yuri N. Shvachko

arxiv: 1604.05852 · v2 · pith:S6BH4BK4new · submitted 2016-04-20 · ❄️ cond-mat.mtrl-sci

The conducting spin-crossover compound combining Fe(II) cation complex with TCNQ in a fractional reduction state

Yuri N. Shvachko , Denis V. Starichenko , Aleksander V. Korolyov , Eduard B. Yagubskii , Alexander I. Kotov , Lev I. Buravov , Konstantin A. Lyssenko , Vladimir N Zverev

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Olga G. Shakirova Ludmila G. Lavrenova

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classification ❄️ cond-mat.mtrl-sci

keywords tcnqbroadeningcationcomplexspin-crossovertransitionanionassociated

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The radical anion salt [Fe{HC(pz)3}2](TCNQ)3 demonstrating conductivity and spin-crossover transition (SCO) associated with Fe(II) complex cation subsystem has been synthesized and structurally characterized. A pronounced change of the dc resistivity and a robust broadening of the EPR signal triggered by the SCO transition are found. Enhanced EPR line broadening is interpreted in terms of cross relaxation between the TCNQ and Fe(II) spin subsystems

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The conducting spin-crossover compound combining Fe(II) cation complex with TCNQ in a fractional reduction state

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