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arxiv: 1209.0239 · v2 · pith:SIN7MPNYnew · submitted 2012-09-03 · ❄️ cond-mat.str-el · cond-mat.mtrl-sci

Dynamical Jahn-Teller Effect in Spin-Orbital Coupled System

classification ❄️ cond-mat.str-el cond-mat.mtrl-sci
keywords effectspin-orbitalstatecoupledcusbdynamicaljahn-tellerorbital
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Dynamical Jahn-Teller (DJT) effect in a spin-orbital coupled system on a honeycomb lattice is examined, motivated from recently observed spin-liquid behavior in Ba$_3$CuSb$_2$O$_9$. An effective vibronic Hamiltonian, where the superexchange interaction and the DJT effect are taken into account, is derived. We find that the DJT effect induces a spin-orbital resonant state where local spin-singlet states and parallel orbital configurations are entangled with each other. This spin-orbital resonant state is realized in between an orbital ordered state, where spin-singlet pairs are localized, and an antiferromagnetic ordered state. Based on the theoretical results, a possible scenario for Ba$_3$CuSb$_2$O$_9$ is proposed.

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