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arxiv: 1408.3920 · v1 · pith:SK4CWAYTnew · submitted 2014-08-18 · ⚛️ physics.chem-ph

Commutator expansions in NMR diffusometry

classification ⚛️ physics.chem-ph
keywords gradientcommutatorderivedexpansionslimitmomentspulseshort
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In this paper commutator expansions for solving the Bloch-Torrey's equation are derived. An exact solution for free diffusion in a constant magnetic field gradient is found. Furthermore the moments of the signal in the short gradient pulse limit for spins confined to a restricted geometry are derived. The moments are tested numerically against the known solution of diffusing spins between two perpendicular plates in the short gradient pulse limit.

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