Perovskite BaCrO₃: completing a materials system with an anomalous Mott transition
classification
❄️ cond-mat.mtrl-sci
cond-mat.str-el
keywords
bacroanomalousinsulatingmottotherperovskitetransitionantiferromagnetism
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We have synthesized and characterized laser-deposited film samples of perovskite BaCrO_{3}, a missing member of the perovskite-chromate family. The BaCrO_{3} films have a substantially larger lattice constant than other chromates, are insulating, and exhibit weak ferromagnetism likely associated with canted antiferromagnetism. Comparison with the other sister compounds CaCrO_{3} and SrCrO_{3} suggest an anomalous Mott transition where magnetism is independent of whether the compound is metallic or insulating
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