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arxiv: 1501.00975 · v1 · pith:VIMS7WC3new · submitted 2015-01-05 · 🪐 quant-ph

Group theoretical analysis of a quantum-mechanical three-dimensional quartic anharmonic oscillator

classification 🪐 quant-ph
keywords grouptheoryanharmonicapplicationoscillatorquantum-mechanicalquarticsymmetry
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This paper illustrates the application of group theory to a quantum-mechanical three-dimensional quartic anharmonic oscillator with $O_{h}$ symmetry. It is shown that group theory predicts the degeneracy of the energy levels and facilitates the application of perturbation theory and the Rayleigh-Ritz variational method as well as the interpretation of the results in terms of the symmetry of the solutions . We show how to obtain suitable symmetry-adapted basis sets.

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