Neutron Diffraction Studies on Temperature Driven Crystallographic Anisotropy in FeVO4 Multiferroic: Evidence of Strong Magnetostructural Correlations

Ajay Tiwari; Ambesh Dixit; Sagarmal Kumawat; Sudhindra Rayaprol

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Neutron Diffraction Studies on Temperature Driven Crystallographic Anisotropy in FeVO4 Multiferroic: Evidence of Strong Magnetostructural Correlations

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arxiv 1903.04913 v1 pith:VYKJSH67 submitted 2019-03-12 cond-mat.mtrl-sci

Ajay Tiwari , Sagarmal Kumawat , Sudhindra Rayaprol , Ambesh Dixit This is my paper · ORCID

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We used temperature-dependent neutron diffraction measurements on FeVO4 to understand the temperature driven anisotropy and observed that the maximum change for a and b lattice parameters in conjunction with a large contraction in angle \beta\ as a function of temperature. The least changes are observed for the c lattice parameter and in \gamma\ angle. From these structural parameters, it can be said that, FeVO4 exhibits large structural anisotropy with lowering temperature. The large change in lattice parameters in magnetic phases i.e. below 22 K explains the strong magnetostructural coupling in FeVO4.

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