Accurate mapping of multilevel Rydberg atoms on interacting spin-1/2 particles for the quantum simulation of Ising models

We study a system of atoms that are laser-driven to $nD_{3/2}$ Rydberg states and assess how accurately they can be mapped onto spin-$1/2$ particles for the quantum simulation of anisotropic Ising magnets. Using non-perturbative calculations of the pair interaction potentials between two atoms in the presence of both electric and magnetic fields, we emphasize the importance of a careful selection of the experimental parameters in order to maintain the Rydberg blockade and avoid excitation of unwanted Rydberg states. We then benchmark these theoretical observations against experiments using two atoms. Finally, we show that in these conditions, the experimental dynamics observed after a quench is in good agreement with numerical simulations of spin-1/2 Ising models in systems with up to 49 spins, for which direct numerical simulations become intractable.