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The Gibbs paradox revisited from the fluctuation theorem with absolute irreversibility

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arxiv 1506.04468 v6 pith:XEXJQB3G submitted 2015-06-15 cond-mat.stat-mech

classification cond-mat.stat-mech
keywords absolutefluctuationgibbsirreversibilitytheorementropyequivalentfactor
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abstract

The inclusion of the factor $\ln (1/N!)$ in the thermodynamic entropy proposed by Gibbs is shown to be equivalent to the validity of the fluctuation theorem with absolute irreversibility for gas mixing.

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