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arxiv: cond-mat/0505703 · v2 · pith:Y2SYMVLLnew · submitted 2005-05-29 · ❄️ cond-mat.str-el · cond-mat.mtrl-sci

A uniqueness theorem in a density-matrix functional theory

classification ❄️ cond-mat.str-el cond-mat.mtrl-sci
keywords interactionelectronuniquenessdensityeffectivefunctionalsystemterm
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Uniqueness of effective interaction defined in an extension of the Kohn-Sham theory is proved, if the model with a non-degenerate ground state exists and to reproduce a correlation function as well as the single-particle density of an electron system. The two-body interaction term is regarded as a Hubbard-type short range interaction term. The interaction strength is a functional of an element of a two-body reduced density matrix of the electron system. The uniqueness theorem gives a basic principle for effective description of electron systems.

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