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arxiv: cond-mat/0507543 · v2 · pith:Y4BVPTG7new · submitted 2005-07-22 · ❄️ cond-mat.soft · cond-mat.dis-nn

The Shapes of Cooperatively Rearranging Regions in Glass Forming Liquids

classification ❄️ cond-mat.soft cond-mat.dis-nn
keywords glasstemperaturetransitionchangecooperativelycorrelationcrossoverdynamical
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The shapes of cooperatively rearranging regions in glassy liquids change from being compact at low temperatures to fractal or ``stringy'' as the dynamical crossover temperature from activated to collisional transport is approached from below. We present a quantitative microscopic treatment of this change of morphology within the framework of the random first order transition theory of glasses. We predict a correlation of the ratio of the dynamical crossover temperature to the laboratory glass transition temperature, and the heat capacity discontinuity at the glass transition, Delta C_p. The predicted correlation agrees with experimental results for the 21 materials compiled by Novikov and Sokolov.

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