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arxiv 2301.09288 v1 pith:Z4FXIQSY submitted 2023-01-23 cond-mat.str-el

Evidence of electron correlation and weak bulk plasmon in SrMoO₃

classification cond-mat.str-el
keywords bulkspectracorrelationelectronelectronicplasmonsatellitesurface
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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We investigate the electronic structure of highly conducting perovskite SrMoO$_{3}$ using valence band photoemission spectroscopy and electronic structure calculations. Large intensity corresponding to coherent feature close to Fermi level is captured by density functional theory (DFT) calculation. An additional satellite at $\sim$ 3 eV binding energy remains absent in DFT, hybrid functional (DFT-hybrid) and dynamical mean field theory (DFT + DMFT) calculations. Mo 4$d$ spectra obtained with different surface sensitive photoemission spectroscopy suggest different surface and bulk electronic structures. DFT + DMFT spectral function is in excellent agreement with the coherent feature in the bulk Mo 4$d$ spectra, revealing moderate electron correlation strength. A large plasmon satellite and signature of strong electron correlation are observed in the surface spectra, while the bulk spectra exhibits a $weak$ plasmon satellite.

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