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arxiv: 1702.05125 · v1 · pith:ZAWM5MOFnew · submitted 2017-02-16 · ❄️ cond-mat.mtrl-sci · cond-mat.other

Comments on the claimed observation of the Wigner-Huntington Transition to Metallic Hydrogen

classification ❄️ cond-mat.mtrl-sci cond-mat.other
keywords hydrogenmetallicreflectivitydatapressuretransitiondiaselectron
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In their recent work Dias and Silvera (Science 2017) claim to have observed the Wigner-Huntington transition of hydrogen to a metallic state (MH) at a pressure of 495 GPa at low temperatures. The evidence for this transition is based on a high electron carrier density deduced from a Drude free electron model fitted to the reflectivity of the sample. Based on our analysis of the reflectivity data we find no convincing evidence for metallic hydrogen in their published data. The pressure determination is also ambiguous - it should be ~630 GPa according to the presented Raman spectrum. For comparison, we present our own data on the observation of highly reflecting hydrogen at pressures of 350-400 GPa. The appearance of metallic reflectivity is accompanied with a finite electrical conductivity of the sample. We argue that the actual pressure in the experiment of Dias and Silvera is likely below 400 GPa. In this case the observed enhanced reflectivity would be related to the phase transformation to conductive state published in arXiv:1601.04479.

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Cited by 1 Pith paper

Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score.

  1. Comment on: Observation of a first order phase transition to metal hydrogen near 425 GPa

    cond-mat.other 2019-07 unverdicted novelty 1.0

    Comment asserts that claimed metallic hydrogen at 425 GPa provides no new evidence of the insulator-metal transition and prior studies already reported comparable results.