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Investigation Solvation Dynamics and Isomerization of Dye IR-140 Using pump supercontinuum-probing Technique

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arxiv physics/0111019 v1 pith:ZIKVCGKQ submitted 2001-11-06 physics.chem-ph physics.optics

classification physics.chem-phphysics.optics
keywords ir-140solventsbeendynamicsisomerizationprocesspumpsolvation
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The solvation dynamics and isomerization process of an organic dye, IR-140, in polar solvents and nonpolar solvents have been investigated using pump supercontinuum-probing (PSCP) technique. In all solvents, the dynamics exhibits solvent-dependent. Solvent induced spectral shifts of the absorption and emission spectra of IR-140 have also been studied in a variety of solvents. At the same time, the photoisomerization process has been examined. The approximate energy-band structure of IR-140 was also supposed firstly.

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