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arxiv: 1808.04979 · v2 · pith:ZZY5NSM2new · submitted 2018-08-15 · ❄️ cond-mat.mtrl-sci

La-Doped BaSnO₃ Electron Transport Layer for Perovskite Solar Cells

classification ❄️ cond-mat.mtrl-sci
keywords bandelectronperovskitetransportalignmentbasnocellsla-doped
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Due to the photo-instability and hysteresis of TiO$_2$ electron transport layer (ETL) in perovskite solar cells (PSCs), novel electron transport materials are highly demanded. Here, we show ideal band alignment between La-doped BaSnO$_3$ (LBSO) and methyl ammonium (MA) lead iodide perovskite (MAPbI$_3$). The CH$_3$NH$_3$PbI$_3$/La$_x$Ba$_{(1-x)}$SnO$_3$ interface forms a stable all-perovskite heterostructure. The selective band alignment is manipulated with band gap renormalization by La-doping on the Ba site. LBSO shows high mobility, photo-stability, and structural stability, promising the next generation ETL materials.

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