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arxiv: cond-mat/0101407 · v1 · submitted 2001-01-26 · ❄️ cond-mat.soft

Sedimentation profiles of systems with reentrant melting behavior

classification ❄️ cond-mat.soft
keywords densityalphaprofilessedimentationfluidgravitationalhighmelting
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We examine sedimentation density profiles of star polymer solutions as an example of colloidal systems in sedimentation equilibrium which exhibit reentrant melting in their bulk phase diagram. Phase transitions between a fluid and a fluid with an intercalated solid are observed below a critical gravitational strength $\alpha^{*}$. Characteristics of the two fluid-solid interfaces in the density profiles occurring in Monte Carlo simulations for $\alpha < \alpha^{*}$ are in agreement with scaling laws put forth in the framework of a phenomenological theory. Furthermore we detect density oscillations at the fluid-gas interface at high altitudes for high gravitational fields, which are verified with density functional theory and should be observable in surface scattering experiments.

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