pith. sign in

arxiv: cond-mat/0103605 · v1 · submitted 2001-03-29 · ❄️ cond-mat.soft

Continuous phase transition in polydisperse hard-sphere mixture

classification ❄️ cond-mat.soft
keywords transitioncontinuousphasepolydispersepreviousableaccurateadjust
0
0 comments X
read the original abstract

In a previous paper (J. Zhang {\it et al.}, J. Chem. Phys. {\bf 110}, 5318 (1999)) we introduced a model for polydisperse hard sphere mixtures that is able to adjust its particle-size distribution. Here we give the explanation of the questions that arose in the previous description and present a consistent theory of the phase transition in this system, based on the Percus-Yevick equation of state. The transition is continuous, and like Bose-Einstein condensation a macroscopic aggregate is formed due to the microscopic interactions. A BMCSL-like treatment leads to the same conclusion with slightly more accurate predictions.

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.