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arxiv: cond-mat/0311478 · v1 · submitted 2003-11-20 · ❄️ cond-mat.stat-mech

Ionic criticality : an exactly soluble model

classification ❄️ cond-mat.stat-mech
keywords criticalitytextitchargecorrelationdensityexactlyioniclength
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Gas-liquid criticality in ionic fluids is studied in exactly soluble spherical models that use interlaced sublattices to represent hard-core \textit{multi}component systems. Short range attractions in the uncharged fluid drive criticality but charged ions do not alter the universality class. Debye screening remains exponential \textit{at} criticality in charge-symmetric 1:1 models. However, \textit{asymmetry} couples charge and density fluctuations in a direct manner: the charge correlation length then diverges precisely as the density correlation length and the Stillinger-Lovett rule is violated \textit{at} criticality.

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