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arxiv: cond-mat/0401153 · v1 · submitted 2004-01-10 · ❄️ cond-mat.stat-mech

Transport properties of dense fluid argon

classification ❄️ cond-mat.stat-mech
keywords enskogtheoryargondensefluidpropertiestransportadaptations
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We calculate using molecular dynamics simulations the transport properties of realistically modeled fluid argon at pressures up to $\simeq 50GPa$ and temperatures up to $3000K$. In this context we provide a critique of some newer theoretical predictions for the diffusion coefficients of liquids and a discussion of the Enskog theory relevance under two different adaptations: modified Enskog theory (MET) and effective diameter Enskog theory. We also analyze a number of experimental data for the thermal conductivity of monoatomic and small diatomic dense fluids.

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