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arxiv: cond-mat/0409081 · v1 · submitted 2004-09-03 · ❄️ cond-mat.mtrl-sci

Nonlinear instability of density-independent orbital-free kinetic energy functionals

classification ❄️ cond-mat.mtrl-sci
keywords energykineticfunctionalsorbital-freearticlebelowboundedclass
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We study in this article the mathematical properties of a class of orbital-free kinetic energy functionals. We prove that these models are linearly stable but nonlinearly unstable, in the sense that the corresponding kinetic energy functionals are not bounded from below. As a matter of illustration, we provide an example of an electronic density of simple shape the kinetic energy of which is negative.

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