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arxiv: cond-mat/0502352 · v1 · submitted 2005-02-15 · ❄️ cond-mat.soft

Analogy of the slow dynamics between the supercooled liquid and the supercooled plastic crystal states of difluorotetrachloroethane

classification ❄️ cond-mat.soft
keywords dynamicsplasticsupercooledstatesanalogycrystalcrystalsdifluorotetrachloroethane
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Slow dynamics of difluorotetrachloroethane in both supercooled plastic crystal and supercooled liquid states have been investigated from Molecular Dynamics simulations. The temperature and wave-vector dependence of collective dynamics in both states are probed using coherent dynamical scattering functions $S(Q,t)$. Our results confirm the strong analogy between molecular liquids and plastic crystals for which $\alpha$-relaxation times and non-ergodicity parameters are controlled by the non trivial static correlations $S(Q)$ as predicted by the Mode Coupling Theory. The use of infinitely thin needles distributed on a lattice as model of plastic crystals is discussed.

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