Magnetic moments of W 5d in Ca2CrWO6 and Sr2CrWO6 double perovskites
classification
❄️ cond-mat.mtrl-sci
keywords
magneticmomentca2crwo6doubleorbitalperovskitessr2crwo6agreement
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We have investigated the magnetic moment of the W ion in the ferrimagnetic double perovskites Sr2CrWO6 and Ca2CrWO6 by X-ray magnetic circular dichroism (XMCD) at the W L(2,3) edges. In both compounds a finite negative spin and positive orbital magnetic moment was detected. The experimental results are in good agreement with band-structure calculations for (Sr/Ca)2CrWO6 using the full-potential linear muffin-tin orbital method. It is remarkable, that the magnetic ordering temperature, TC, is correlated with the magnetic moment at the 'non-magnetic' W atom.
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