Spontaneous thermal runaway as an ultimate failure mechanism of materials

The first theoretical estimate of the shear strength of a perfect crystal was given by Frenkel [Z. Phys. 37, 572 (1926)]. He assumed that as slip occurred, two rigid atomic rows in the crystal would move over each other along a slip plane. Based on this simple model, Frenkel derived the ultimate shear strength to be about one tenth of the shear modulus. Here we present a theoretical study showing that catastrophic material failure may occur below Frenkel's ultimate limit as a result of thermal runaway. We demonstrate that the condition for thermal runaway to occur is controlled by only two dimensionless variables and, based on the thermal runaway failure mechanism, we calculate the maximum shear strength $\sigma_c$ of viscoelastic materials. Moreover, during the thermal runaway process, the magnitude of strain and temperature progressively localize in space producing a narrow region of highly deformed material, i.e. a shear band. We then demonstrate the relevance of this new concept for material failure known to occur at scales ranging from nanometers to kilometers.