Combination of random-barrier and random-trap models
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The temperature dependence of the diffusion coefficient of particles is studied on lattices with disorder. A model is investigated with both trap and barrier disorder that was introduced before by Limoge and Bocquet (1990 Phys. Rev. Lett. (65) 60) to explain an Arrhenian temperature-dependence of the diffusion coefficient in amorphous substances. We have used a generalized effective-medium approximation (EMA) by introducing weighted transition rates as inferred from an exact expression for the diffusion coefficient in one-dimensional disordered chains. Monte Carlo simulations were made to check the validity of the approximations. Approximate Arrhenian behavior can be achieved in finite temperature intervals in three- and higher-dimensional lattices by adjusting the relative strengths of the barrier and trap disorder. Exact Arrhenian behavior of the diffusion coefficient can only be obtained in infinite dimensions.
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