Interference of a first-order transition with the formation of a spin-Peierls state in alpha'-NaV2O5?
classification
❄️ cond-mat
keywords
transitionalphaaroundfirst-orderformationnav2o5resultsspin-peierls
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We present results of high-resolution thermal-expansion and specific-heat measurements on single crystalline alpha'-NaV2O5. We find clear evidence for two almost degenerate phase transitions associated with the formation of the dimerized state around 33K: A sharp first-order transition at T1=(33+-0.1)K slightly below the onset of a second-order transition at T2onset around (34+-0.1)K. The latter is accompanied by pronounced spontaneous strains. Our results are consistent with a structural transformation at T1 induced by the incipient spin-Peierls (SP) order parameter above T2=TSP.
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