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arxiv: cond-mat/9809326 · v1 · submitted 1998-09-24 · ❄️ cond-mat.stat-mech

Sluggish Kinetics in the Parking Lot Model

classification ❄️ cond-mat.stat-mech
keywords approachkineticsdensitymodelratevariesadsorbingalgebraic
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We investigate, both analytically and by computer simulation, the kinetics of a microscopic model of hard rods adsorbing on a linear substrate. For a small, but finite desorption rate, the system reaches the equilibrium state very slowly, and the long-time kinetics display three successive regimes: an algebraic one where the density varies as $1/t$, a logarithmic one where the density varies as $1/ln(t)$, followed by a terminal exponential approach. A mean-field approach fails to predict the relaxation rate associated with the latter. We show that the correct answer can only be provided by using a systematic description based on a gap-distribution approach.

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