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arxiv: cond-mat/9903260 · v3 · submitted 1999-03-17 · ❄️ cond-mat.soft

Apparent finite-size effects in the dynamics of supercooled liquids

classification ❄️ cond-mat.soft
keywords systembecomesdynamicseffectsfinite-sizesizesmallsupercooled
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Molecular dynamics simulations are performed for a supercooled simple liquid with changing the system size from N=108 to $10^4$ to examine possible finite-size effects. Although almost no systematic deviation is detected in the static pair correlation functions, it is demonstrated that the structural $\alpha$ relaxation in a small system becomes considerably slower than that in larger systems for temperatures below $T_c$ at which the size of the cooperative particle motions becomes comparable to the unit cell length of the small system. The discrepancy increases with decreasing temperature.

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