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arxiv: cond-mat/9906308 · v1 · submitted 1999-06-20 · ❄️ cond-mat.soft

Beta-relaxation of non-polymeric liquids close to the glass transition

classification ❄️ cond-mat.soft
keywords lossglassfrequencypeaktransitionarrheniusbeta-relaxationclose
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Dielectric beta-relaxation in a pyridine-toluene solution is studied close to the glass transition. In the equilibrium liquid state the beta loss peak frequency is not Arrhenius (as in the glass) but virtually temperature-independent, while the maximum loss is strongly temperature-dependent. Both loss peak frequency and maximum loss exhibit thermal hysteresis. A new annealing-state independent parameter involving loss and loss peak frequency is identified. This parameter has a simple Arrhenius temperature-dependence and is unaffected by the glass transition.

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